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There are basically three types of ion-exchange mechanisms. (1). Cation exchange, (2). Anion-exchange, and (3). Copolymeric mixed-mode ion-exchange. Figure 22 shows a dichotomous key that can be used to determine which ion-exchange column is the best for your application. Table 10 shows a list of common ion-exchange sorbents and their structures. Table 11 shows typical analytes, washes, and elution solvents for ion-exchange bonding. 10 Cation Exchange Extractions Cation-exchange sorbents are negatively charged while basic analytes are manipulated to carry a positive charge.
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Annalen 272:156, 1892. 5 Reed, L. Proc. Chem. Soc. 9:123, 1893. 6 Day, D. T. Amer. Phil. Soc. 36:112, 1897. 7 Engler, C. and Albrecht, E. Z. Angew. Chemie 889, 1901. 8 Tswett, M. S. Ber. Stoch. Bat. Geo. 24:384, 1906. , Ber. 64:1349, 1906. 10 Kuhn, R. and Lederer, E. Naturwiss. 19:306, 1931. , 24:384, 1906. 12 Martin, A. J. P. and Synge, R. L. M. Biochem. J. 35:1358, 1941. , Gordon, A. , and Martin, A. J. P. Biochem. J. 38:224, 1944. , Reichender, F. Liebigs Ann. , 546 (1941). 15 Kirchner, J. , Keller, G.