Organic Chemistry

Download BarCharts QuickStudy Organic Chemistry Fundamentals by Inc. BarCharts PDF

By Inc. BarCharts

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1926, 6, 110. 8 Milobedski and Sachnowski, Chem. Zbl. 1918, 1, 911. 4 McCombie, Saunders and Stacey, J. Chem. Soc. 1945, p. 380. 44 SYNTHETIC METHODS the complete removal of the tertiary base is sometimes difficult, particularly the elimination of traces of pyridine from triethyl phosphite. We therefore carried out the reaction between phosphorus trichloride and ethyl alcohol in the absence of a tertiary base1 and obtained a 90 per cent yield of pure diethyl hydrogen phosphite (III): r P \ iCl + H:0-C 2 H 5 ' ' /OC 2 H 5 > P<-0-C2H5 X 0-C 2 H 5 /OH > P<-0-C2H5 + C2H6C1.

Chem. org. Naturst. 1952, 8, 97. 20 Chapter II NOMENCLATURE OF ESTERS CONTAINING PHOSPHORUS In view of the rapid growth of the organic chemistry of phosphorus since 1939, considerable attention has been paid to nomenclature. It has not always been easy to achieve agreement among workers in different parts of the world as to the most logical, convenient and simple system. It may not be out of place therefore to trace the inner history of some of the changes and developments that have taken place.

8 It may be noted that the oculomotor centre in the brain is also controlled by impulses passing from the higher centres. g. during sleep and surgical anaesthesia. The higher centres can be directly stimulated by morphine, thus causing pin-point pupil. Fear and excitement causes dilatation of the pupil as does adrenaline. Ergotoxine paralyses the sympathetic and causes constriction. Accommodation (fig. 9). The lens of the eye is suspended by the zonula (suspensory ligament) consisting of delicate transparent fibres attached on the one hand to the ciliary body and on the other to the elastic capsule covering the lens.

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