By C.H. Heathcock
Quantity 2 bargains quite often with the addition reactions of delocalized carbanions (enolates) and their man made kinfolk (metalloenamines, enol ethers, allyl organometallics) with carbonyl compounds, imines and iminium ions. significant emphasis is put on C-C bond-forming reactions akin to the aldol and Mannich reactions. Acylation reactions also are integrated during this quantity. a number of themes that experience no longer formerly been reviewed are lined, together with using enzymatic aldol reactions in synthesis and the Passerini-Ugi reactions.
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Extra resources for Additions to C-X &pgr;-Bonds, Part 2, Volume 2
J. Clin. Oncol. C. , Pharmacol. Ther. R. , Prog. Med. Chem. , 1984, 21, 169 (rev) Iguchi, H. , Cancer Chemother. Pharmacol. , 1985, 15, 132 (Pirarubicin) Traganos, F. , Cancer Res. M. , Drugs Exp. Clin. Res. , 1985, 11, 1 (A 489, rev) Castegnaro, M. , IARC Sci. Publ. , 1985, 49, (disposal) Kimura, Y. , Bull. Chem. Soc. Jpn. M. , J. Med. Chem. S. Pat. , 1986, 4 610 977, (Univ. of Tennessee ); CA , 105, 209343v (AD 198) Allman, T. , Can. J. Chem. , 1987, 65, 2405 (pmr, conformn) Barbieri, B. , Cancer Res.
Chem. Ber. , 1975, 108, 759; 772; 780 (struct, ir, uv, ms, nmr) Mizobuchi, S. , J. Antibiot. , 1986, 39, 1776 (deriv) Aldgarose A-69 3-C-[1-(Carboxyoxy)ethyl]-4,6-dideoxyD-ribo-hexose intramol. ,3-ester, 9CI. -carbonate O O O CH3 H3C 2 O 3 8 O OH2 C HO MeO OMe O O b-D-Pyranose-form Me glycoside: [17184-26-8] Cryst. (CH2Cl2/Et2O). Mp 178-1808 (175-1768). 86 in MeOH). n 1770 cm-1 (CO). 357 Cryst. (Et2O). Mp 105-1078. 69 in MeOH). A. , Tetrahedron , 1967, 23, 3893 (Me gly, isol, struct) Paulsen, H.
244 Widely distributed in nature. One of the four principal nucleosides of nucleic acid. Antiarrhythmic agent. Cardiac depressant. Launched 1989. Cryst. (H2O). Sol. H2O, MeOH; poorly sol. Me2CO, hexane. Mp 234-2368. 7 in H2O). 4 (258). 88 (calc). Component of numerous preparations. lmax 259 (e 15400) (H2O). lmax 260 (e 15100) (H2O) (Berdy). -LD50 (mus, ipr) 500 mg/kg. -Adenylic acid. 224 Mp 1958 dec. 0 in H2O). -adenylate. -Butylphosphoryladenosine. 331 Prod. by Nocardia sp. Inducer of biosynth.