Organic Chemistry

Download Activation and Catalytic Reactions of Saturated Hydrocarbons by A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov PDF

By A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov

This monograph is dedicated to the activation and numerous variations of saturated hydrocarbons (alkanes), i.e. reactions observed by means of the C--H and C--C bond cleavage. Alkanes are the most components of oil and traditional gasoline, and accordingly are the critical feedstocks for the chemical undefined. however, those ingredients are recognized to be the least reactive natural compounds. distinctive realization is paid to the lately came upon alkane activations in the presence of steel complexes, that are defined in additional aspect. as well as the reactions of saturated hydrocarbons that are the major subject of this booklet, the activation of C--H bonds in arenes or even olefins and acetylenes are thought of. The monograph may be important not just when you have an interest in the activation of alkanes and different hydrocarbons through steel complexes, but additionally for experts in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. a few elements of the monograph should be of curiosity for experts in inorganic and natural chemistry, theoretical chemistry, biochemistry or even biology, and additionally when you paintings within the petrochemical undefined, commercial natural synthesis and biotechnology.

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G) Green, M. L. H. J. Chem. , Dalton Trans. 1986, 2469. Watson, P. L. J. Am. Chem. Soc. 1983, 105, 6491. 14. Shul’pin, G. ; Nizova, G. ; Nikitaev, A. T. J. Organomet. Chem. 1984, 276, 115. 15. (a) Renneke, R. ; Hill, C. L. Angew. Chem. 1988, 100, 1583. (b) Periana, R. ; Taube, D. ; Evitt, E. ; Löffer, D. ; Wentrecek, P. ; Masuda, T. Science, 1993, 259, 340. ; Sen, A. J. Am. Chem. Soc. 1996, 118, 4574. 16. C. J. Am. Chem. Soc. 1979, 101, 1032. ; Hirobe, M. Heterocycles 1995, 40, 867. CHAPTER II HYDROCARBON TRANSFORMATIONS THAT DO NOT INVOLVE METALS OR THEIR COMPOUNDS n this chapter we will briefly survey the main types of hydrocarbon transformations that occur without the participation of solid metals or oxides and metal complexes.

14. Shul’pin, G. ; Nizova, G. ; Nikitaev, A. T. J. Organomet. Chem. 1984, 276, 115. 15. (a) Renneke, R. ; Hill, C. L. Angew. Chem. 1988, 100, 1583. (b) Periana, R. ; Taube, D. ; Evitt, E. ; Löffer, D. ; Wentrecek, P. ; Masuda, T. Science, 1993, 259, 340. ; Sen, A. J. Am. Chem. Soc. 1996, 118, 4574. 16. C. J. Am. Chem. Soc. 1979, 101, 1032. ; Hirobe, M. Heterocycles 1995, 40, 867. CHAPTER II HYDROCARBON TRANSFORMATIONS THAT DO NOT INVOLVE METALS OR THEIR COMPOUNDS n this chapter we will briefly survey the main types of hydrocarbon transformations that occur without the participation of solid metals or oxides and metal complexes.

Marks, T. J. J. Am. Chem. Soc. 1984, 106, 2214. (f) Jones, W. ; Feher, F. J. Organometallics 1983, 2, 562. (g) Green, M. L. H. J. Chem. , Dalton Trans. 1986, 2469. Watson, P. L. J. Am. Chem. Soc. 1983, 105, 6491. 14. Shul’pin, G. ; Nizova, G. ; Nikitaev, A. T. J. Organomet. Chem. 1984, 276, 115. 15. (a) Renneke, R. ; Hill, C. L. Angew. Chem. 1988, 100, 1583. (b) Periana, R. ; Taube, D. ; Evitt, E. ; Löffer, D. ; Wentrecek, P. ; Masuda, T. Science, 1993, 259, 340. ; Sen, A. J. Am. Chem. Soc. 1996, 118, 4574.

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